How Winter Deicers Impact Concrete- and What We Can Do About It.

Every winter, maintenance crews turn to deicing chemicals to keep roads and sidewalks safe for drivers and pedestrians. These products are extremely effective at preventing accidents—but they can also contribute to long-term damage in concrete pavements. Understanding how deicers work, why certain chemicals are more harmful than others, and what can be done to protect concrete can help communities make informed decisions about winter road maintenance.
Anti-Icing vs. Deicing: What’s the Difference?
Winter road treatments fall into two main categories:
Anti-icing is a preventive approach. Liquid or solid chemicals are applied before snow or ice begins to accumulate. The goal is to stop ice from bonding to the pavement in the first place.
- Applied before a storm begins
- → Prevents snow and ice from bonding to the pavement.
Deicing, on the other hand, is used after snow and ice are already present. These treatments melt accumulated ice so it can be plowed away.
- Applied after accumulation
- → Melts existing ice so it can be plowed or cleared away.
Both strategies rely on chemicals—either liquid or solid forms like rock salt—and often include abrasives such as sand to improve winter traction.
What Chemicals Are Used?
The most common commercial grade deicing products are aqueous (water-based) chloride solutions, including:
- Sodium chloride (NaCl)
- Calcium chloride (CaCl₂)
- Magnesium chloride (MgCl₂)
- Calcium magnesium acetate (CMA)
- Potassium acetate (KAc)
Among these, MgCl₂ and CaCl₂ are especially popular because they are affordable, easy to apply, and work over a broad range of temperatures. These chemicals are often applied at high concentrations to dry pavement before a storm—particularly during anti-icing operations. This means fully concentrated solutions can be drawn into the concrete surface and joints.
How Deicers Work—and Why Concentration Matters
A deicer’s melting effectiveness depends on both:
- The chemical type, and
- Its concentration
Higher concentrations melt ice at colder temperatures, but they also increase the likelihood of concrete deterioration. In fact, salt concentration is one of the most critical factors in determining whether concrete will deteriorate. Deicers—no matter which type—amplify natural freeze–thaw damage by:
- Increasing moisture saturation in concrete pores
- Causing thermal shock during rapid melting
- Raising osmotic pressures due to changes in pore chemistry and concentrated salt solutions
- Allowing salt crystals to form within the concrete, which expand and break the concrete apart, further leach calcium into the surrounding concrete- both significantly reducing strength.
These mechanisms can lead to scaling, spalling, and surface distress, especially around joints.

Chemical Deicer Attack: A New and Growing Concern
The Chemistry Behind the Damage
Concrete contains calcium hydroxide, a byproduct of cement hydration. When CaCl₂ or MgCl₂ penetrates the concrete in the presence of water, it can react with the calcium hydroxide to form calcium oxychloride.
This compound is:
- Highly expansive, and
- Capable of generating damaging crystallization pressures within concrete pores
The result?
Surface spalling, cracking, and deterioration, most often near joints where moisture and chemicals accumulate.
The Role of Salt Concentration
Low concentrations of deicing chemicals typically do not trigger chemical oxychloride reactions. In such cases, the damage observed is mostly natural physical freeze–thaw deterioration.
But at higher concentrations—especially those applied during anti-icing—the chemical reaction becomes the dominant cause of surface damage. Concentrations are often far higher than necessary for melting, greatly increasing the risk. This is why salt concentration cannot be overstated as a key factor in winter concrete distress.
Why Anti-icing Can Make the Problem Worse
Anti-icing often applies high-concentration chemicals to dry pavement. This combination creates a perfect storm:
- Dry concrete absorbs liquid quickly, pulling concentrated chemicals deep into pores and joints.
- If precipitation is light or delayed, the solution remains highly concentrated for long periods.
- Pooling in poorly draining joints leads to even higher local concentrations.
During deicing operations (applied onto existing snow/ice), melting water immediately dilutes the chemicals, which reduces the likelihood of chemical attack—but repeated freeze-thaw cycles can still concentrate salts over time.
Good Concrete Starts Before Winter Maintenance Begins
Preventing both chemical and physical freeze–thaw deterioration begins long before deicers hit the pavement. It starts in the concrete ready-mix plant and extends through construction.
1. Quality Concrete Mix Design
- Proper water-to-cement ratios
- A well-developed air-void entrainment system, designed to relieve hydraulic and osmotic pressures as ice forms
2. Sound Construction Practices
- Minimize surface disturbance to protect the air-void system
- Ensure adequate curing to support hydration and strength
- Use proper joint design, placement, and depth
- Correctly install tie bars and reinforcement to prevent restraint-related joint failures
3. Well-Functioning Joints Are Critical
Joints serve as pressure relief points and drainage pathways. When they function properly, they prevent brine from pooling and concentrating.
However, joints can fail if:
- Tie bars restrain them too tightly
- Debris clogs drainage paths
- Joints are placed incorrectly
- The joint never “activates” (i.e., the crack doesn’t form beneath the saw cut)
Failed joints allow high-concentration salt solutions to seep into surrounding concrete, triggering accelerated chemical attack.
Conclusion
Deicers are essential tools for winter safety, but their effects on concrete are complex and often underestimated. While physical freeze–thaw damage has long been understood, chemical reactions—particularly those involving MgCl₂ and CaCl₂—are an emerging challenge.
With thoughtful mix design, good construction practices, and careful winter maintenance strategies, it’s possible to balance public safety with long-term pavement durability. As research progresses, industry practices will continue evolving to better protect both people and infrastructure.
REFERENCES
*Chemical Deicers and Concrete Pavement: Impact and Mitigation., March 2018 FHWA-HIF-008,DEPARTMENT OF TRANSPORTATION
Durability of concretes exposed to high concentrations of CaCL2 and MgCl2., June 2022 – NATIONAL CENTER FOR BIOTECHNOLOGY INFORMATION
Researchers uncover hidden deicer risks affecting bridge health., Studies led by Xianming Shi A/Prof., April 2019 – WASHINGTON STATE UNIVERSITY
Effect of Chloride-based Deicers on Reinforced Concrete Structures., July 2010., Final Report prepared for WSDOT – WSDOT RESEARCH REPORT







